Abstract
Here, we discuss a particle-based approach to deal with systems of many identical quantum objects (particles) that never employs labels to mark them. We show that it avoids both methodological problems and drawbacks in the study of quantum correlations associated with the standard quantum mechanical treatment of identical particles. The core of this approach is represented by the multiparticle probability amplitude, whose structure in terms of single-particle amplitudes we derive here by first principles. To characterize entanglement among the identical particles, this new method uses the same notions, such as partial trace, adopted for non-identical ones. We highlight the connection between our approach and second quantization. We also define spin-exchanged multipartite states which contain a generalization of W states to identical particles. We prove that particle spatial overlap plays a role in the distributed entanglement within multipartite systems and is responsible for the appearance of non-local quantum correlations.
This article is part of a discussion meeting issue ‘Foundations of quantum mechanics and their impact on contemporary society’.
1. Introduction
Identical quantum objects (e.g. qubits, atoms, quantum dots, photons, electrons and quasi-particles) typically are the basic ‘particles’ forming the building blocks of quantum-enhanced devices [1–11]. Characterizing the quantum properties of composite systems of identical particles is therefore important from both the fundamental and technological points of view. In quantum mechanics, owing to their indistinguishability, identical particles are not individually addressable and require specific treatments which differ from those used for non-identical (distinguishable) particles.
In the standard quantum mechanical approach (SA) to dealing with identical particles, the first step is to assume that they are not, marking them with unobservable labels [12,13]. This is the only place where non-observable quantities occur, being quantum states defined by complete sets of commuting observables. SA requires that the system is described by states whose structure is constrained to be symmetric (bosons) or antisymmetric (fermions) with respect to the labels [13–15]. So an intrinsic entanglement is present, even for independently prepared separate particles, which is attributable to the particle fundamental indistinguishability. This has given rise to different viewpoints about physical meaning and assessment of this part of entanglement [16–33]. For some, the entanglement due to indistinguishability is considered to be present but unusable in a state of independently prepared distant particles [12]; for others it is seen as a merely formal artefact even when the particles are brought to overlap [34,18]. Establishing the physical nature of identical particle entanglement is, therefore, crucial to identifying its role as a resource for quantum information and communication processing [11,17,22,35–42].
Recently, a different approach has been introduced [32] which describes the quantum states of identical particles without introducing unobservable labels. This non-standard approach (NSA), so far limited to two identical particles, exhibits peculiar advantages from both the conceptual and practical viewpoints, and is linked in particular to the treatment of their quantum correlations. In fact, from the beginning it avoids the existence of entanglement due to unobservable labels. The particle-based approach to identical particles uses, for quantifying the entanglement in these systems, the same well-established notions and tools commonly employed for non-identical particle systems, such as the basis-independent partial trace and von Neumann entropy. In this sense, the particle-based approach differs from other known approaches and is closer to the typical scenario of quantum information theory. This NSA has enabled the following to be shown: the existence of the Schmidt decomposition for identical particles [33] (showing that it is universally valid for both identical and not identical particles); a new efficient generation scheme of multipartite W entangled states [43]; and the definition of an operational framework to directly exploit entanglement due to indistinguishability for quantum information protocols [42]. Here, we reconsider the NSA from a fundamental perspective and generalize it to a system of many identical particles.
The paper is organized as follows. In §2, we briefly present, as an example, some immediate problematic implications for the use of quantum SA in the characterization of entanglement between identical particles. In §3, we give the formalism and the tools of the NSA for a system of N identical particles in a pure state. We obtain the many-particle probability amplitudes from first principles. In §4, we generalize states of non-identical particles to a system of identical ones. In §5, we demonstrate the role of spatial overlap in entanglement evaluation for three identical qubits, and the Bell inequality violation for independently prepared identical particles within an operational framework. We finally summarize our conclusion in §6.
2. Problematics of the standard quantum mechanical approach to identical particles
Ordinarily the SA treats identical particles as if they were not, and in general this works well. Here, we briefly describe how this method gives rise to unnecessary methodological and practical difficulties, especially when particle quantum correlations are involved. These difficulties arise because of the adoption of unphysical labels to mark particles and of the required (anti)symmetrization of states with respect to labels [13].
In the usual label approach to identical particles, the (anti)symmetrization implies that each of them has the same probability amplitude of occupying each single-particle state of the system. This justifies Peres’s observation that ‘only one fermion can occupy a quantum state is a not accurate statement’ [12].
Other counterintuitive aspects with identical particles arise when one considers time-dependent problems. In fact, when a particle is created locally (LOCC processes) in a given location, it instantaneously appears in a far away location provided that another identical labelled particle is already present there. To make this point clear, we consider a helium atom 4He in the state |He′E〉 on Earth and an ionized atom 4He+ in the state Figure 1. Simultaneous generation on the Earth and on the Andromeda galaxy of two identical helium atom states.
plus an electron in the state |eA〉 on the Andromeda galaxy (subscripts E and A representing the spatial localization of states on Earth and Andromeda). Being at the beginning, all the involved particles are distinguishable, and the global state is the tensor product |Ψ0−〉=|He′E〉⊗|He+A〉⊗|eA〉. At the universal time t=0, 4He′ is scattered in 4He and simultaneously ion 4He+ on Andromeda absorbs the electron e, forming the atom 4He (figure 1). At t=0+ on Earth and on Andromeda, two identical bosons appear in states |HeE〉 and |HeA〉. In the SA, the identical atoms were distinguished with labels 1 and 2, and the global state is (except for a normalization factor)
. Thus, while at t=0− each particle is separately localized on either E or A, at t=0+ each of the two helium atoms simultaneously occupies both states on E and A. This approach requires acceptance of the notion, for instance, that the non-relativistic helium atom generated at t=0+ in A, because of the identical particle in E, instantaneously develops a non-zero amplitude of being there, although the events (0+E,0+A) are space-like separated. Moreover, the global state of the two identical particles |Ψ0+〉, when expressed in terms of labelled particles, has the form of an entangled state even if they are independently prepared far away from each other and never interact. In other words, it seems that in the standard operational framework based on local operations and classical communication (LOCC), these two particles become entangled even if they are in a separable state at the beginning. To cope with this situation, that is, to avoid observable effects of the unobservable labels, ‘we must now convince ourselves that this entanglement is not matter of concern’ [12].

The viewpoint of the SA thus makes a straightforward discussion of correlations (such as entanglement) in systems of identical particles problematic, because of the difficulty in formally separating the real part of correlations from the unphysical one arising from labels. Moreover, such a description hinders the use of a partial trace and the von Neumann entropy, as normally done for non-identical particles [16]. In fact, indistinguishability implies that the particles are not individually addressable and so the common reduced density matrix obtained by the partial trace is meaningless. This issue has originated different treatments for a faithful quantification of identical particle entanglement [16–33].
3. Non-standard approach to many identical particles
Here, we consider a recently introduced approach to deal with identical particles that does not adopt unphysical labels to mark them [32]. This NSA eliminates ab ovo the conceptual strains inherent in the SA and also allows us to directly focus on the treatment of physical quantum correlations. So far, it has been applied to the case of two identical particles [32,33]. We now re-examine this approach from a fundamental viewpoint and extend it to a system of many identical particles.
Let us take a 1-particle state |{α}〉 characterized by a complete set of commuting observables {α}. The state of two identical particles with two generic sets of commuting observables is |{α1},{α2}〉, which we write in a short hand notation as |{α1},{α2}〉:=|1,2〉. The sets 1 and 2 may coincide, in this way giving |{α1},{α1}〉:=|1,1〉. Generalizing to the case of N identical particles, the elementary global quantum state |ϕ(N)〉 is

In the example illustrated in figure 1, being the single-particle states at t=0+ given by |HeE〉 and |HeA〉, using (3.1) the global final state is |HeE,HeA〉. This means that one helium atom is localized in E and one in A. Entanglement with respect to labels simply does not appear and the question of whether the two identical atoms are entangled does not even need to be posed.
For one particle, the relevant quantities to obtain probabilities are the transition amplitudes 〈k′|k〉 to find the particle in the exit state |k′〉 if it is prepared in the entry state |k〉. In the NSA, this must be generalized for N particles. The absence of labels implies that the state of equation (3.1) is not separable in terms of tensor products of 1-particle states and is a holistic entity.
We assume that the transition amplitude from the state |1,…,N〉 to the state |1′,…,N′〉, namely 〈1′,…,N′|1,…,N〉, can be expressed in terms of the 1-particle probability amplitudes. This is natural when each 1-particle state in the transition amplitude is localized in a region far away from the others (figure 2a,b). Under this condition, the cluster decomposition principle, stating that distant experiments provide independent outcomes [12], allows us to express the total transition amplitude as the product of the 1-particle ones as 〈1′,2′,…,N′|1,2,…,N〉=〈1′|1〉〈2′|2〉⋯〈N′|N〉 (figure 2a), and more generally as


Figure 2. (a,b) Cluster decomposition principle. The set {P1,…,PN} represents the N! permutations of the 1-particle states |1〉,…,|N〉. (c) General case where there is spatial overlap among the entry 1-particle states in which the global system is prepared (red cloud) and among the exit ones on which the system is measured (blue cloud). (d) Particular situation where only all the entry 1-particle states do not overlap (red clouds). The coloured clouds represent the spatial regions occupied by the states written within them. The arrows show the transition of each |k〉 state (k=1,…,N) towards one or more |k′〉 states (k′=1′,…,N′).
When both the entry and exit 1-particle states are localized in overlapping spatial regions (figure 2c), to maintain the property of linearity, the N-particle probability amplitude can be expressed as a linear combination of N! terms of the form (3.2)


, where P−1 is the inverse permutation (
) (see appendix A). We now consider the simplest case of two identical particles, for which any αP is real and the 2-particle probability amplitude, using (3.3), is



Generalizing the symmetric and antisymmetric expression (3.7) to an arbitrary number N of identical particles, we can write

.We remark that, in the situations represented by figure 2b and only in these cases, one can write 〈1′,…,N′|P1,…,PN〉:=(〈1′|⊗⋯⊗〈N′|)(|P1〉⊗⋯⊗|PN〉). Therefore, for calculation purposes |1,…,N〉≃|1〉⊗⋯⊗|N〉. This is not true if there is overlap either among the 1-particle entry states or among the exit ones (figure 2c,d). In this sense, probability amplitudes are more fundamental than quantum states.
An arbitrary elementary normalized N-identical particle state is defined as

. |Φ(N)〉 is expressed in terms of single-particle states as a single-state vector, which is to be compared with the linear combination of the N! product state vectors in the SA approach:
.The next step is to define the action of operators in the NSA approach. We limit ourselves to an arbitrary 1-particle operator A(1) that acts on each 1-particle state at a time: A(1)|k〉:=|A(1)k〉. Its action on N-particle states is naturally defined as

(a) Partial trace
To calculate the partial trace, we have to define a product operation between bra and ket of a different number of particles. In particular, the M-particle partial trace of an N-particle state is expressed as

is a collective M-particle orthonormal basis (
being a normalization constant). This operation corresponds to measuring the states of M identical particles without registering the outcomes. When M=N,
just coincides with the normalized probability amplitude.We now consider the simple case in which M=1. Given a single-particle orthonormal basis {|k′〉}, we have to define the product 〈k′|⋅|1,2,…,N〉. Given the operator A(1)=|j′〉〈k′| and using equation (3.10), its action on an N-particle state |1,…,N〉 can be written as

and shifted the state
from the kth site to the first one (
indicates the lack of the kth state). Let us express now the ket in the second line of equation (3.12) as follows:
, where we have introduced with the symbol ∧ a non-separable symmetric external product between different kets, valid for boson and fermions, that we call the wedge product (for fermions this product is Penrose’s wedge product defined in terms of labelled states [44]). For N identical particles, we have
and
. Moreover,
. The wedge product coincides with the multiplication operation of the exterior algebra associated with the symmetrized Hilbert space
. Therefore, equation (3.12) can be written as


Considering the 1-particle basis {|k′〉} and taking the 1-particle projection operator
, the probability pk′ of finding one of the identical particles in the state |k′〉 is given (except for a normalization factor) by
. Being the action of the 1-particle identity operator
on an N-particle state
, the normalized reduced (N−1)-particle pure state
and the probability pk′ are

, which corresponds to the sum of probabilities of incompatible outcomes.Specifically, the normalized 1-particle partial trace of an N-particle state is

We now take the case M=2. The relevant dot product is

. If N=2 equation (3.17) coincides with the 2-particle probability amplitude given by (3.7).The 2-particle unity operator is
, where
is the 2-particle projection operator. The normalized reduced (N−2)-particle pure state
and its probability
are


We point out that, in the NSA, once the relevant reduced density matrix is obtained, the entanglement between the bipartition of M and (N−M) particles can be measured by the von Neumann entropy
. Moreover, knowledge of the reduced density matrices of all the possible bipartitions of the system allows the qualitative assessment of the genuine multipartite entanglement of the pure state of N identical particles, as usually done for non-identical particles [35]. Note that, as the identical particle entanglement intrinsically depends on both global state structure and observation measurements [31,42], one has to specify the partial trace and the reduced density matrix corresponding to a desired operational framework [42]. This result differs from what is obtained in the SA, where the partial trace cannot be used [16]. We shall analyse identical particle entanglement in §5.
(b) Connection of the non-standard approach with second quantization
Above we have introduced relations between states differing in the number of particles. This suggests a relationship between the NSA to identical particles and second quantization. However, while in the second quantization particles are elementary excitations of fields, our approach applies to any system of identical quantum objects. In the second quantization approach, creation and annihilation operators connect states differing by only one particle and their commutation rules reflect the commutation rules of the fields. In the NSA, the dot products connect states differing for a generic number of particles. Finally, in the second quantization the fundamental role is played by the commutation rules, while in the NSA it is played by the symmetry of the states.
To show the connection between the NSA and the second quantization, we note that equation (3.14) suggests the introduction of a 1-particle annihilation operator






From the symmetry properties of the states, it is simple to obtain the a’s commutation rules. For the 1-particle creation and annihilation operators of equations (3.20) and (3.21), we obtain


4. Properties of some multiparticle states
In this section, we show how some known structures and properties of states of non-identical particles can be generalized to the case of identical particles.
(a) Spin exchanged states
We consider the well-known W entangled state of non-identical particles, which constitutes an important resource state for several quantum information tasks [43,45]. We explicitly describe a single-particle state with the spatial mode ϕi (i=1,…,N) and the pseudospin ↑,↓. The W state has the structure


, while one expects no restriction arising from particle statistics, considering that the two fermions in A have opposite spins. The same problem is thus expected to arise even when the particles are spatially non-overlapping but non-local measurements are performed. Hence, the form of the W state of equation (4.1) for identical particles does not work in general.We define a spin-exchanged state (SPES) as a suitable linear combination of elementary states where only particle pseudospins are exchanged, that is,

is the normalization constant of each state entering the sum and
is the global normalization constant. When σ1= ↑ and σ2=⋯=σN= ↓, the SPES represents a generalization of the W state for identical particles valid for bosons and fermions under any circumstances. Other states of interest are obtained from (4.3) for different pseudospin conditions; for instance, assuming a ring configuration of the N particles and taking σ1=⋯=σM= ↑ and σ(M+1)=⋯=σN= ↓ such states can represent a linear combination of spin block systems in the ring chain.(b) Separability of spatial and spin degrees of freedom
For any elementary state of non-identical particles, the spatial and spin degrees of freedom, being associated with the individual particle, are independent and separable. This is not the case for elementary states of identical particles.
As mentioned above, the essence of the NSA is the absence of labels and the consequent holistic form of the states that are not separable in tensor products of single-particle states. For a single particle, we have |ϕσ〉≡|ϕ〉⊗|σ〉, i.e. the spatial part of the state can be treated separately from the pseudospin one. Instead, for two identical particles, when ϕ1≠ϕ2 and σ1≠σ2, it is |ϕ1σ1,ϕ2σ2〉≠|ϕ1,ϕ2〉⊗|σ1,σ2〉, so measures of position and pseudospin operators may not be independent. One may ask which structure a state of identical particles must have in order that spatial and pseudospin degrees of freedom are independent from each other.
To fix our ideas, let us take the state



, spatial and pseudospin degrees of freedom can be separated as |Φ±〉=|φ1,φ2〉η±⊗|σ,τ〉±, where the subscripts indicate the symmetry of the state: |κ,χ〉γ=γ|χ,κ〉γ. For such a state, entanglement of pseudospins can be treated independently of the spatial degrees of freedom. When σ=↑ and τ=↓, |Φ±〉 are two Bell states. It is moreover immediate to show that an entangled state of the form
is always equivalent to |ϕ1ϕ2〉η⊗(|σ,σ〉±|τ,τ〉).5. Applications
We now apply the NSA formalism and tools described above to examine entanglement properties of identical particle pure states by partial traces and local measurements.
(a) Effects of the spatial overlap on the entanglement in the spin-exchanged state
We consider the SPES for three qubits placed in separated spatial modes L (left), C (centre) and R (right). Following equation (4.3), it has the form


measures the entanglement of pseudospins between the bipartitions L (one particle) and C–R (two particles). This entropy is less than 1 and independent of the type of particle. As expected, this result coincides with that obtained, under the same conditions, for the non-identical particle W state.We now consider the case when the spatial wave functions of two particles completely overlap, in particular C=L. From equation (4.3), the corresponding (unnormalized) SPES is


and
. The corresponding von Neumann entropy is

. This result highlights the effect of spatial overlap and of the nature of the particles on the bipartite entanglement of three identical particles.(b) Bell inequality violation for identical particles
We now apply the NSA to study a state of identical particles within a Bell test scenario [46,47], using a suitable operational framework [42].
We take two independently prepared identical qubits, one being in the spatial mode ψ with pseudospin ↑ and the other one in the spatial mode ψ′ with pseudospin ↓. The global state is therefore

In this context, it is useful to introduce the probability amplitudes of finding the two particles in the two separated spatial regions L (left) and R (right), l=〈L|ψ〉, l′=〈L|ψ′〉, r=〈R|ψ〉 and r′=〈R|ψ′〉. Following Lo Franco & Compagno [42], we choose the 2-particle basis in the subspace defined by the two separated regions, namely BLR={|L↑,R↑〉,|L↑,R↓〉,|L↓,R↑〉,|L↓,R↓〉}, and we project the state (5.6) onto this subspace by means of the projector
, obtaining the pure state

is

We now use the pseudospin observable
(S=L,R) with eigenvalues ±1, where OS is the unit vector in an arbitrary direction in the spin space and
is the Pauli matrices vector. The Clauser–Horne–Shimony–Holt (CHSH)–Bell inequality [46] in this context is

is the Bell function expressed in terms of the correlation functions of the pseudospin observables and
indicates the measurement in a direction different from that of
[48]. A well-known procedure [49,50] allows us to express the maximum value of the Bell function
in terms of the concurrence (entanglement) [35] of the state |ΨLR〉 as

when C(ΨLR)>0, i.e. whenever there is spatial overlap between ψ and ψ′ and the local measurements are performed inside the overlap region (that is, all the four probability amplitudes l, l′, r, r′ are non-zero). The violation of the CHSH–Bell inequality identifies the presence of non-local correlations between the pseudospin outcomes in the regions L and R.Therefore, spatial overlap between wave functions associated with independently prepared identical particles can generate non-locality effects which can be tested in quantum optical scenarios [51] and then exploited to implement quantum information or communication processes [42].
6. Conclusion
In this work, we have presented an alternative way to deal with sets of identical quantum objects. These objects, which can constitute building blocks of a complex system, can be considered as ‘particles’ in general, not coinciding with elementary excitations of quantum fields. This NSA to identical particles differs from the SA one in that it never makes use of labels to mark particles. The core of NSA is played by the probability amplitude between N-particle states. We have derived this multiparticle probability amplitude by first principles, that is, the cluster decomposition principle, stating that distant experiments provide independent outcomes [12], and linearity with respect to 1-particle states. The NSA is universal in that it works for any type of particle. It exhibits methodological advantages compared with the SA by avoiding the problematics arising there from the necessary symmetrization with respect to unobservable labels. This occurs, for example, when identical particles are generated in far away regions with each particle instantaneously developing a non-zero probability amplitude of being in space-like separated places.
The NSA also enables technical advantages with respect to SA by supplying essential tools which are not usable in the latter, such as projective measurements and partial trace. As by-products of such tools, one straightforwardly obtains the von Neumann entropy associated with the reduced density matrix, which estimates the entanglement of a general bipartition of N identical particles. We have moreover introduced generalized products between vector spaces of different dimensions, showing that these can be connected with generalized annihilation and creation operators. When these operators connect states differing for one excitation, they coincide with the operators in the second quantization. While in the latter the commutation rules between annihilation and creation operators derive from the field ones, here they are determined by the many-particle probability amplitude.
We have shown that some non-identical particle-entangled states, such as the W states, cannot be used tout court for identical particles. Within the NSA, we have introduced the SPESs which contain the extension of W states to identical particles and allow the quantitative role of spatial overlap to be demonstrated in the bipartite entanglement of multiparticle states. A new by-product of the NSA is that indistinguishability in the presence of spatial overlap of independently prepared identical particles gives rise to exploitable non-local entanglement.
Finally, the NSA provides a very convenient way for describing a system of N identical particles and their entanglement. The results of this work pave the way to further studies concerning the characterization of identical particle systems, such as multipartite coherence, correlations other than entanglement and dynamics under noisy environments.
Data accessibility
This article has no additional data.
Authors' contributions
G.C. and R.L.F. conceived and designed the study. A.C. performed the calculations. All authors discussed the results and contributed to the preparation of the manuscript.
Competing interests
The authors declare that they have no competing interests.
Funding
No funding has been received for this article.
Acknowledgements
G.C. acknowledges W. G. Unruh for useful observations during the Royal Society Meeting. R.L.F. thanks U. Marzolino for discussions.
Appendix A
In the case of the one-dimensional representation of the permutation group, the N-particle probability amplitude can be written as



, in which Q−1 is the inverse permutation of Q. Comparing the last two equations, we find that Q=P−1 and
.Appendix B
Here, we give the explicit derivation of equation (3.27).
— We first consider the action of a(m′,n′)a†(m,n) on a generic N-particle state |ϕ(N)〉 (see equation (3.1)). Using equation (3.17), we find:
where
.— The action of
on the same state is

From the above equations, we obtain

Footnotes
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