NH4F-assisted one-pot solution synthesis of hexagonal ZnO microdiscs for efficient ultraviolet photodetection

One-pot solution method to grow large hexagonal ZnO microdiscs with the aid of ammonium fluoride (NH4F) mineralizer has been realized. The size, morphology, crystallinity and optical properties of the synthesized ZnO microdiscs can be efficiently modulated by the concentration of NH4F. X-ray diffraction and scanning electron microscopy analyses illustrate that hexagonal ZnO microdiscs achieved at 0.03 M NH4F concentration have larger disc size and narrower full-width value at half maximum of (002) peak. It implies better crystal quality compared with those from other additive concentrations. Photoluminescence results also demonstrate the same trend. These results indicate that with proper addition of NH4F, the crystal quality of ZnO microdiscs has been improved and defects have been suppressed. Furthermore, a UV photodetector has been fabricated by simply transferring the ZnO microdiscs grown with 0.03 M NH4F onto a p-type silicon substrate. The device exhibits photosensitive behaviour at 365 nm UV light illuminating when −0.6 V is applied. The response time as well as recovery time is less than 0.1 s. The relatively large photoresponsivity of 1.19 A W−1 with power consumption less than 10 nW makes it possible in application field of highly efficient low power consumption UV detection.

GF, 0000-0002-3880-9943 One-pot solution method to grow large hexagonal ZnO microdiscs with the aid of ammonium fluoride (NH 4 F) mineralizer has been realized. The size, morphology, crystallinity and optical properties of the synthesized ZnO microdiscs can be efficiently modulated by the concentration of NH 4 F. X-ray diffraction and scanning electron microscopy analyses illustrate that hexagonal ZnO microdiscs achieved at 0.03 M NH 4 F concentration have larger disc size and narrower full-width value at half maximum of (002) peak. It implies better crystal quality compared with those from other additive concentrations. Photoluminescence results also demonstrate the same trend. These results indicate that with proper addition of NH 4 F, the crystal quality of ZnO microdiscs has been improved and defects have been suppressed. Furthermore, a UV photodetector has been fabricated by simply transferring the ZnO microdiscs grown with 0.03 M NH 4 F onto a p-type silicon substrate. The device exhibits photosensitive behaviour at 365 nm UV light illuminating when 20.6 V is applied. The response time as well as recovery time is less than 0.1 s. The relatively large photoresponsivity of 1.19 A W 21 with power consumption less than 10 nW makes it possible in application field of highly efficient low power consumption UV detection.
considerable attention in revealing the growth mechanism of its nanostructures. Before applying in such fields, revealing the growth mechanism of its various nanostructures (nanowires [1], nanotubes [2], nanobelts [3], nanoflowers [4], etc.) seems to be of more importance [5,6]. Most of the ZnO nanostructures used in optoelectronic devices are nanorod-like [7 -9]. Owing to the high Q-factors, however, ZnO nanostructures such as micro-/nano-discs or plates, with suppressed c-axis orientation, are emerging and regarded as important building blocks for nanoscale optoelectronic devices [10]. Various fabrication methods have been reported to fabricate ZnO microdisc structure [11 -13]. In order to obtain high-quality ZnO microdiscs, vapour phase methods, such as vapour phase transport (VPT) and chemical vapour deposition (CVD), have been widely used. The photoluminescence (PL) properties of ZnO nano-/micro-discs with whispering-gallery mode [14,15] and the growth mechanism have been studied [13,16]. However, the VPT and CVD methods need high temperature in the process, leading to high energy cost, which is not good for our environment. A simple and economic solution method with low growth temperature should be more favourable. The ZnO microdiscs obtained through solution method always have small size in diameter; low crystal quality is reported in the literature. Such small ZnO discs are very difficult to use in devices for optoelectronic devices [17,18]. Furthermore, single ZnO microdisc-based ultraviolet (UV) photodetectors are seldom reported. Thus, large ZnO microdiscs with excellent crystal quality are highly expected. Ammonium fluoride (NH 4 F) is an acidic mineralizer and is reported to play an important role in promoting the growth rate and improving the crystal quality of GaN and ZrO 2 in the ammonothermal growth method [19 -22]. Several F-doped ZnO films are realized through magnetron sputtering or pulsed laser deposition [23 -25]. However, rare work is shown in the growth of ZnO nano-or micro-disc structures [26].
In this work, we report a simple one-pot solution method for the synthesis of large ZnO hexagonal microdiscs with the assistance of NH 4 F at a relatively low temperature (958C). We found that NH 4 F concentration significantly affects the ZnO growth process. The morphology and crystal quality of ZnO microdiscs also vary with the NH 4 F concentration. With proper NH 4 F concentration, the diameter of ZnO hexagonal microdiscs can be as large as 16 mm. The growth rate and crystal quality of ZnO microdiscs are improved by adding a suitable amount of NH 4 F in the nutrient solution. A ZnO microdisc/p-Si heterojunction diode has been fabricated by transferring the individual ZnO microdisc grown with the additive of 0.03M NH 4 F onto a p-Si substrate for ultraviolet photodetection. The device exhibits good rectifying characteristic (approx. 245 at + 1 V). The response time and recovery time is less than 0.1 s under UV illumination (365 nm, 4.1 mW cm 22 ). Furthermore, the device has shown good reproducibility with a large responsivity of about 1.19 A W 21 , while the power consumption is less than 10 nW.

Experimental section
All reagents in this work are of analytical grade and used without further purification. The ZnO microdiscs were synthesized via a facile one-pot solution process. The precursor solution contained an aqueous solution of 10 mM zinc nitrate hexahydrate (Zn(NO 3 ) 2 . 6H 2 O), 10 mM hexamethylenetetramine (HMT), 1 mM sodium citrate (Na 3 C 6 H 5 O 7 ) and different amounts of NH 4 F (0, 0.01, 0.03 and 0.05 M). The sodium citrate was frequently used as a surfactant to control the shape of ZnO crystals. The as-prepared solution was transferred to sealed glass jars for solution treatment at 958C for 7 h in an oven. After that, the glass jars were cooled down to room temperature (RT) naturally and ZnO microdiscs were formed in the solution. Then, the obtained solution containing the ZnO microdiscs was dropped onto a clean p-Si substrate (1 -10 V cm). The samples were annealed at 5008C in air for 6 h to form ZnO microdisc/p-Si heterojunction UV detectors. Finally, the In-Ga alloy was scraped onto the backside of the p-Si substrate as anode and the probe was directly pressed onto the microdisc as cathode. All the measurements were applied at RT.
The morphology of the ZnO microdiscs was characterized by a scanning electron microscopy (SEM, JEOL JSM-6700F). The crystal structure and phase composition were characterized by X-ray diffraction (XRD, Bruker AXS, D8 Advance). The photoluminescence (PL) measurements were carried out under a 325 nm He-Cd laser at RT and the emission was collected via a HORIBA Jobin-Yvon monochromator. Raman spectra were collected through a HORIBA Jobin-Yvon LabRam HR system equipped with a 488 nm laser. The current -voltage (I-V) curves were measured by a Keithley 4200 rsos.royalsocietypublishing.org R. Soc. open sci. 5: 180822 semiconductor parameter analyser. The photoresponsivity was measured by a home-built testing system, with a xenon light source and a spectrometer.

Results and discussion
The SEM images of ZnO microdiscs obtained at 958C for 7 h with different NH 4 F concentrations in the nutrient solution are shown in figure 1a-d. As sodium citrate is provided in the precursor solution acting as the capping agent to selectively inhibit ZnO growth along the c-axis, near-round shaped ZnO microdiscs with approximately 7.5 mm in diameter are obtained without the addition of NH 4 F, as shown in figure 1a. The ZnO microdiscs are randomly distributed on the substrate without preferential orientation. Some of them are vertically grown on the silicon substrate. This is consistent with the reported results in the literature [27 -30]. As an acidic mineralizer, NH 4 F has been reported to increase the crystallinity and crystal size of various materials grown by the solution method [22,31 -33]. In this work, it is obvious to figure out that NH 4 F greatly affects the growth of ZnO microdiscs. Highly regular shape ZnO microdiscs with clear hexagonal edges were obtained with the addition of NH 4 F, as shown in figure 1b-d. Most ZnO microdiscs were uniformly distributed on the silicon surface along with ZnO c-axis. When the amount of NH 4 F is small (0.01 M), the shape of ZnO microdiscs changes from near-round to hexagonal, along with a notable change in their diameters. By raising the concentration of NH 4 F to 0.03 M, the diameter of the ZnO microdiscs is increased and ZnO microdiscs with diameter as large as 16 mm can be obtained. As shown in figure 1e-f, the top surface of ZnO microdiscs presents a multi-layered structure, while the bottom surface is smooth. However, further increasing the concentration of NH 4 F to 0.05 M, the distribution of the microdiscs on substrate became very sparse and some of them are also vertically grown on the silicon substrate. The thickness of the ZnO microdiscs adding 0, 0.01, 0.03 and 0.05 M is 1.5, 2, 7 and 4 mm, respectively, as shown in electronic supplementary material, figure S1. The changes in the morphology, density and diameter of ZnO microdiscs indicate that NH 4 F has really played an important role in the growth of ZnO nanostructures. As an acidic mineralizer, NH 4 F not only promotes the growth of ZnO nanostructure along the polar, semipolar and nonpolar faces but also remarkably increases their growth rates and enhances the crystallization quality [19,22]. The solubility of the precursors can be promoted significantly and the chemical potential of the solution could be increased through the addition of F 2 which would be more favourable for nanostructure growth. F 2 also can decrease the solution viscosity, and therefore make the mobility of ions improved [22]. The growth reactions are similar to those reported in the literature [34,35], as shown in equations (3.1) and (3.2). In these equations, equation (3.1) dominates the whole reaction. As is known, the surfactant sodium citrate can remarkably inhibit the growth of ZnO along c-axis direction, thus resulting in the appearance of round ZnO microdiscs, as shown in figure 1a. While adding NH 4 F, the growth rates of ZnO crystals are greatly promoted except for the c-axis direction, so it leads to larger hexagonal ZnO microdiscs with clear edges and multi-layered structures as shown in figure 1b,c. However, excessive NH 4 F (0.05 M) would apparently decrease the crystal size and suppress the yield of ZnO microdiscs, which is probably due to the fact that a large amount of added NH 4 þ ions might hinder the HMT hydrolysis to produce OH 2 (equation (3.1)) and promotes the formation of ZnF(OH) due to the excess F 2 , all of which would impede the crystallization of ZnO nuclei [36]. X-ray photoelectron spectroscopy (XPS) measurement was conducted to determine the F-doping concentration. The results are shown in electronic supplementary material, figure S2. respectively. This result also shows that the F 2 ions prefer to be absorbed on the surface of ZnO. Because the F concentration obtained from XPS, which shows almost the surface status, is larger than that from EDS, which interprets the bulk information. Owing to the large electronegativity, the absorbed F atoms can eliminate the oxygen vacancy, thus improving the crystal quality. The effects of NH 4 F on the crystallinity of the ZnO microdiscs are further investigated through XRD and PL measurements. The results are shown in figures 2 and 3, respectively. Figure 2a shows the XRD patterns of the samples grown with different NH 4 F concentrations. As depicted in figure 2a, the XRD patterns are indexed as the typical hexagonal wurtzite-type ZnO and no diffraction peaks from impurities can be found. Although all samples have similar XRD patterns, the full width at half maximum (FWHM) of peaks belonging to (100), (002) and (101) planes vary with concentration of the additive NH 4 F. It can be seen clearly from figure 2b that the FWHM of XRD peaks first decreased with NH 4 F concentration. At 0.03 M NH 4 F, the FWHM reaches the smallest value among the samples, indicating the highest crystallinity. When the concentration of NH 4 F additive reaches 0.05 M, the quality of crystallization becomes retrogressed, which is in accord with the SEM results observed in figure 1. This result proves that proper concentration of NH 4 F additive can promote crystallization and improve crystalline quality, as we mentioned before.
Photoluminescence measurement is used to investigate the defect existing in as-grown ZnO. Figure 3 shows the normalized PL spectra of ZnO microdiscs with different amounts of NH 4 F. Without adding NH 4 F, the main UV emission centres at 389 nm (near-band-edge (NBE) emission of ZnO) and the visible emission centres at 625 nm (related to oxygen interstitial (O i ) and oxygen vacancy (V O ) defects [37][38][39]). After the addition of NH 4 F, the UV emission presents a blue shift from 389 nm to 379 nm and the visible emission diminishes gradually with increased NH 4 F from 0 to 0.03 M. This means that the crystallinity of ZnO microdiscs gets better with the increase of NH 4 F concentration from 0 to 0.03 M. The blue shift of the UV peak in the PL spectra of ZnO microdiscs is probably attributed to the Burstein -Moss effect due to the n-type doping [38,40] by F 21 and the improvement of crystallinity and the reduction of defects. The defect energy levels have been filled up that make the NBE emission blue shifts. The weakening of visible emission delivers other evidence for enhanced crystal quality. However, further increasing the concentration of NH 4 F to 0.05 M would result in both changes of the peak position in the near UV and visible emission due to the superfluous F 2 that participated in chemical etching. The blue to green light emission was enhanced, while UV and yellow to red emissions were suppressed. The similar phenomenon was reported before in the literature where the researchers found absorption peaks at 455 and 586 nm in their absorption spectra of F-doped ZnO samples [39]. Although F 2 can passivate V O defect due to large electronegativity which can lead to the suppression of V O -related emissions, excess F 2 absorbed on the surface may induce other defect rsos.royalsocietypublishing.org R. Soc. open sci. 5: 180822 energy levels. This destroys the surface of ZnO microdiscs and increases defects. Although there is no impurity phase in the XRD spectrum, the excess F 2 might be absorbed to the surface of the microdiscs forming defect states, resulting in the poor optical properties.
As shown in figure 4, all Raman spectra obtained from ZnO microdiscs with different amounts of NH 4 F exhibit the main peaks at 436.71 cm 21 attributed to the E high 2 vibration mode of ZnO, though the intensities have some variations [41]. The peaks at 437, 332, 380 and 584 cm 21 of ZnO microdiscs correspond to E high 2 , E high 2 À E low 2 , A 1 (TO) and E 1 (LO) mode, respectively [42]. The peak at 520 cm 21 originates from Si substrate. The intensities of E high 2 band of Raman spectra are strengthened along with the increase of NH 4 F concentration from 0 to 0.03 M, suggesting that the NH 4 F additive plays an important role in promoting crystal growth and crystallization improvement. However, the decreased intensity of E high 2 band with 0.05 M NH 4 F may be caused by the deteriorated crystal quality, which is proved by XRD and PL measurements results discussed below. Hence, we have found that with 0.03 M NH 4 F additive, the relatively large and regular hexagonal ZnO microdisc can be achieved, with better crystal quality and lower defect concentration. Thus, a ZnO microdisc/p-Si photodetector has been fabricated through a simple transfer method for demonstration. Figure 5a shows the schematic illustration of the as-fabricated n-ZnO microdisc/p-Si UV detector. The probe was directly contacted onto the microdisc as the cathode and the InGa alloy was scraped onto the p-Si substrate as the anode. Figure 5b depicts the I-V characteristics of the detector under dark and UV irradiation (365 nm, approx. 4.1 mW cm 22 ). Without light illumination, the device reveals good rectification ratio of about 245 at + 1 V, which is better than those of n-ZnO nanorod/p-Si devices  reported in the literature [43]. When the UV light (365 nm) illuminated the device, the current increases and the device show a sensitivity of 400%, which is calculated by the following equation:  where, I light and I dark are the currents measured with and without the UV light (365 nm) illumination, respectively. The ideality factor n of the heterojunction device is calculated to be 2.93, according to the method reported in the literature, as shown in the inset of figure 5b [44]. The ideality factor of this device is larger than that of an ideal p-n junction, which may be due to the imperfect interfaces between ZnO microdiscs and p-Si. Figure 5c depicts figure S3. Besides the stability, another important parameter to evaluate the performance of a photodetector is response speed. Figure 5d shows the response and recovery characteristic of the device. It is easy to figure out that the fast response and recovery time are less than 0.1 s, accompanying slow response and recovery component. Through exponent fitting, we can deduce that the slow response time is 12.92 s and the slow recovery time is 3.58 s. The rather short response and recovery time benefit from the improved crystal quality. The slow response and recovery parts originate from the oxygen absorbing and desorbing process [45,46]. The UV detector can reach a relatively large photoresponsivity of 1.19 A W 21 at 20.6 V bias, which is better than the reported ZnO nanorod photodetector [47]. The spectral photoresponsivity in electronic supplementary material, figure S4 shows a relatively high response in the UV region. This relatively high response originates from the ZnO microdiscs [48].

Conclusion
In summary, large hexagonal ZnO microdiscs were synthesized through a simple and low-energy-cost one-pot solution method with the aid of ammonium fluoride (NH 4 F). The growth rate and crystal quality of ZnO hexagonal microdiscs can be improved with proper NH 4 F concentration. ZnO microdiscs grown as large as 16 mm in diameter with 0.03 M NH 4 F can be achieved. Enhanced UV emission was obtained and the visible emission was suppressed with proper concentration of NH 4 F. The blue to green light emission of the ZnO disc was enhanced, while UV and yellow to red emissions were suppressed with further addition of NH 4 F. Based on the results, an ultraviolet n-ZnO microdisc/p-Si photodetector with a good rectifying characteristic (approx. 245 at + 1 V) has been fabricated. The response and recovery time of the device is less than 0.1 s, under ultraviolet illumination (4.1 mW cm 22 ). The photoresponsivity can reach a relatively large value of 1.19 A W 21 , with power consumption less than 10 nW. This kind of n-ZnO microdisc/p-Si device may be useful in highly efficient low power consumption photodetector applications.
Data accessibility. All data generated or analysed during this study are included in this article. Authors' contributions. G.F. and D.Z. designed the study. B.L. and K.Z. grew the samples and wrote the manuscript. Z.C. and Z.S. carried out the measurements. B.L., K.Z. and Z.C. analysed the data. All the authors gave their final approval for publication.
Competing interests. We declare we have no competing interests.